4 grams of hydrogen reacts with some oxygen to make 36 grams of water. Figure out how much oxygen must have been used by applying the law of conservation of mass? Show Solution: According to law of conservation of mass – Mass of reactants = Mass of products Problem : 2 In a chemical reaction 150 g Baking soda mixture containing sodium bicarbonate and vinegar on heating gives 87 g of carbon dioxide gas. What mass of solid residue will left in food? Solution: Here, baking soda mixture (reactant) on heating gives solid residue and carbon dioxide ( products).Here baking soda mixture (reactant) on heating gives solid residue and carbon dioxide ( products). MBaking soda = MSolid residue + MCarbon dioxide Hence, the mass of solid residue is 150g – 87g = 63g. Read first –
Problem : 3 Solution: Problem : 4 A thin strip of iron with a mass of 15.5g is placed into a solution containing 21.0g of copper (II) sulfate and copper begins to form. After some times, the reactions stops because all the copper (II) sulfate has reacted. The iron strip is found to have a mass of 8.5g. The mass of copper formed is found to be 8.60g. What mass of iron (II) sulfate has been formed in the reaction? Solution: So, Mass of iron (II) sulfate = 19.40g Problem : 5 Silicon dioxide, made up of elements silicon and oxygen, contains 46.7% by mass of silicon. With what mass of oxygen will 10 g of silicon combine? Solution: It means, 10g of silicon will contain (10/100) × 53.3 = 5.33 g of oxygen. Problem : 6 When 0.0976g of magnesium was heated in air, 0.1618g of magnesium oxide (MgO) was produced. What is the mass of oxygen needed to produce 0.1618g MgO? Mass is an isolated system. The law of conservation of mass states that the mass can neither be created nor destroyed in a chemical reaction. There is just a rearrangement in the atoms of substances for the formation of compounds. Therefore, the mass of the total system remains constant at any interval of time. This implies that the total masses of reactants is equal to the sum of masses of products and the masses of unreacted reactants. The law of conservation of mass is also termed as the principle of mass conservation. Mass of the total enclosed system at the beginning of the reaction is equivalent to the mass at the termination of the reaction.
Experiment to verify the law of conservation of massThe following experiment can be conducted to verify the law of conservation of mass: Things required to perform the experiment:
The reaction can be visualised as a precipitation reaction, where the insoluble salt separates out as a precipitate. The reaction occurs between the Barium Chloride (BaCl22(aq)) and Sodium Sulphate (Na2SO4(aq)). Both the compounds are taken in aqueous solutions, that is water is taken as the solvent. This is a kind of double displacement reaction. The reaction involved is, BaCl2(aq) + Na2SO4(aq) ————-> BaSO4(aq) + 2NaCl(aq) Rearranging the equation in the iconic form, we get, Ba+(aq) + SO42-(aq) —————> BaSO4(s) The reactants involved in the reaction are barium chloride and sodium sulphate, whereas the products involved are barium sulphate and sodium chloride. Now, we know,
Steps Involved in the Process
Assumptions during the experiment In case of distilled water, density is assumed to be 1g /cc. Things to take care of before the experiment
Observations The following inferences can be drawn from the experiment, Mass of aqueous solution of barium chloride (BaCl2) = 3.6 g Mass of BaCl2 solution = 53.6 g Mass of aqueous solution of sodium sulphate (Na2SO4.10H2O) = 8.05 g Mass of Na2SO4 solution =58.05 g Mass of 50 ml distilled water = 50.0 g Calculating the total mass of reactants, we have, BaCl2 + Na2SO4 = 53.6 + 58.05 = 111.65 g Mass of empty 150 mL beaker,m1 =………………….g Mass of reaction mixture before precipitation, m2= m1+ 111.65 g = ……………………g Final mass of reaction mixture after precipitation, m3 =……………………. g Conclusions When we compare the mass of reactants with those of products, the two masses are considered to be equivalent. This implies that the observed masses, m2 = m3. Hence, the law of conservation of mass is preserved. Sample QuestionsQuestion 1. Where is the law of conservation applicability found? Answer:
Question 2. What is a double displacement precipitation reaction? Answer:
Question 3. Which other reaction type can be used to display the law of conservation of mass? Answer:
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